Abstract
AbstractThe design of spiroorthocarbonate monomers (SOCs) and related structures is discussed with the aim of maximizing monomer polymerizability in the absence of undesirable byproducts. The successful syntheses of N,S‐analogs of aryl‐ and alkaryl‐SOCs are reported; these are monomers of structure magnified image where P and Q are O and OC(CH3)2−, mp 156–158°C; and P and Q are OCH2 and OCH2, mp 148–150°C. As is indicated by infrared spectra, the polymerization of both monomers is initiated by boron trifluoride etherate. © 1993 John Wiley & Sons, Inc.
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More From: Journal of Polymer Science Part A: Polymer Chemistry
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