Design of Ice-free Nanostructured Surfaces Based on Repulsion of Impacting Water Droplets
Materials that control ice accumulation are important to aircraft efficiency, highway and powerline maintenance, and building construction. Most current deicing systems include either physical or chemical removal of ice, both energy and resource-intensive. A more desirable approach would be to prevent ice formation rather than to fight its build-up. Much attention has been given recently to freezing of static water droplets resting on supercooled surfaces. Ice accretion, however, begins with the droplet/substrate collision followed by freezing. Here we focus on the behavior of dynamic droplets impacting supercooled nano- and microstructured surfaces. Detailed experimental analysis of the temperature-dependent droplet/surface interaction shows that highly ordered superhydrophobic materials can be designed to remain entirely ice-free down to ca. -25 to -30 °C, due to their ability to repel impacting water before ice nucleation occurs. Ice accumulated below these temperatures can be easily removed. Factors contributing to droplet retraction, pinning and freezing are addressed by combining classical nucleation theory with heat transfer and wetting dynamics, forming the foundation for the development of rationally designed ice-preventive materials. In particular, we emphasize the potential of hydrophobic polymeric coatings bearing closed-cell surface microstructures for their improved mechanical and pressure stability, amenability to facile replication and large-scale fabrication, and opportunities for greater tuning of their material and chemical properties.
- Research Article
650
- 10.1098/rsta.2000.0689
- Nov 15, 2000
- Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences
This paper reviews the background to and the current status of analyses developed to address the problem of icing on aircraft. Methods for water droplet trajectory calculation, ice accretion prediction, aerodynamic performance degradation and an overview of ice protection system modelling are presented. The paper addresses the issues involved in the development of icing analyses including problem formulation and assumptions, solution techniques, validation and the incorporation of empirical inputs where a purely theoretical approach is not feasible. Results are presented to illustrate the capabilities of the analyses when applied to practical design problems. Recommendations are made for further research.
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235
- 10.1016/j.expthermflusci.2014.04.007
- Apr 18, 2014
- Experimental Thermal and Fluid Science
Freezing of water droplets on solid surfaces: An experimental and numerical study
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23
- 10.1016/j.ijheatmasstransfer.2021.122471
- Jan 20, 2022
- International Journal of Heat and Mass Transfer
A diffusion-enhancing icing theory for the freezing transition of supercooled large water droplet in impact
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50
- 10.1016/j.applthermaleng.2022.119516
- Jan 1, 2023
- Applied Thermal Engineering
Experimental and numerical study on freezing process of water droplets under surfaces with different wettability
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23
- 10.1016/j.ijheatmasstransfer.2022.122955
- May 3, 2022
- International Journal of Heat and Mass Transfer
Freezing dynamics of supercooled micro-sized water droplets
- Research Article
13
- 10.1016/j.tsep.2020.100722
- Sep 15, 2020
- Thermal Science and Engineering Progress
Numerical and experimental analysis of rapid solidification considering undercooling effect during water droplet impact on a substrate
- Research Article
64
- 10.1088/0370-1301/69/10/309
- Oct 1, 1956
- Proceedings of the Physical Society. Section B
A microscope method was used to study the freezing of individual water droplets 9 to 33 microns in diameter formed by condensation on various surfaces and protected with a film of silicone oil. The lowest freezing temperatures were found to be independent of the six surfaces used but dependent upon the volume of the water droplets and the rate of cooling. The results were correlated with those of other observers and it was concluded that homogeneous nucleation occurred in the lowest freezing droplets. Values of the surface free energy for a water-ice interface were calculated.
- Research Article
177
- 10.1016/j.apsusc.2016.12.219
- Dec 29, 2016
- Applied Surface Science
Anti-icing property of bio-inspired micro-structure superhydrophobic surfaces and heat transfer model
- Research Article
3
- 10.3390/pr11010258
- Jan 13, 2023
- Processes
The collision behavior and ice formation of a water droplet are affected by its falling process. In this paper, the two-phase flow of air and a water droplet at a specific temperature is adopted to investigate the processes of falling and freezing of a single water droplet. To track the air–water droplet interface and the temperature distribution, the level-set method and the non-isothermal flow coupling method are used, and the freezing model is added into the water’s control equations. The numerical results indicated that with the initial temperature at 283.15 K and the spherical shape, the water droplet changes to the shape of a straw hat at 293.15 K and a drum at 293.15 K but an oval face in freezing temperatures at 0.10 s. There is an obvious drop in the downward velocity when the water droplet falls in mild temperatures at 0.09 s. The downward velocity of the water droplet in air at sub-zero temperatures has a continuous increase during the time span from 0 s to 0.10 s. There is also an obvious difference when the water droplet impinges on the solid bottom. Lastly, the freezing of sessile water droplets attached on the horizontal surface is helpful to reveal the unique phase change process of water droplets in cold air.
- Research Article
30
- 10.1016/j.colcom.2022.100590
- Jan 26, 2022
- Colloid and Interface Science Communications
The freezing of water droplets placed on metallic surfaces and surfaces lubricated with various silicone oils was studied. The freezing of water droplets placed on inclined and upside-down planes, both bare and coated with silicone oil (that completely coated the water droplets) was also studied. We established that the opening angle of the freezing cone did not depend on neither the spatial orientation of the substrate nor on the coating of the frozen droplet with the silicone oil. The geometrical axis of the freezing cones coincided with the normal to the inclined surface. The opening angle of the freezing tip was not influenced by the volume of the droplet, contact angle hysteresis, the pinning of the triple line, the surface tension of the cloaked droplet, the viscosity of the silicone oil and the spatial orientation of the substrate. The paper supports the universal mechanism of the formation of the freezing tip, based on purely geometrical considerations.
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44
- 10.1016/j.ijheatmasstransfer.2022.123108
- Jun 7, 2022
- International Journal of Heat and Mass Transfer
Experimental study on freezing characteristics of water droplets on cold surfaces
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140
- 10.1016/j.ijheatmasstransfer.2018.02.023
- Feb 20, 2018
- International Journal of Heat and Mass Transfer
An experimental investigation on the unsteady heat transfer process over an ice accreting airfoil surface
- Research Article
54
- 10.1016/j.ijthermalsci.2021.107241
- Aug 26, 2021
- International Journal of Thermal Sciences
Freezing characteristics of deposited water droplets on hydrophilic and hydrophobic cold surfaces
- Conference Article
8
- 10.2514/6.2015-0035
- Jan 2, 2015
- 53rd AIAA Aerospace Sciences Meeting
The in-flight ice formation and accretion are highly dependent on weather conditions that essentially affect the heat transfer capability. When the temperature is sufficiently cold, the heat transfer is adequate to remove all of the latent heat from the collected water. The rate of rime ice accretion is controlled by the droplet collection efficiency. Otherwise, when the heat transfer is inadequate to remove all of the latent heat in collected water, the rate of glaze ice accretion is essentially controlled by the local convective heat transfer, which determines the amount of latent heat removal from the collected water. To better understand the physical details during an ice accretion process, time resolved heat transfer information is important and strongly desired. In this study, a methodology based on infrared thermography was developed to achieve nonintrusive measurements of unsteady heat transfer process over an ice accreting NACA 0012 airfoil. Comprehensive 2-D surface temperature distribution measurements under various icing conditions (e.g. air temperature, liquid water content, and wind speed) were performed in an icing wind tunnel. A heat balance model was formulated based on the current measurement model. The dynamic surface temperature distribution variations were characterized based on the measurements. The temperature variation history at different chordwise positions during ice accretion process was fully recorded and illustrated. Based on the temperature variation history along the airfoil surface, the heat transfer evolution in chordwise direction was evaluated. Finally, The effects of the liquid water content on the heat transfer process were elucidated based on the measurement results.
- Research Article
107
- 10.1016/j.expthermflusci.2017.05.009
- May 17, 2017
- Experimental Thermal and Fluid Science
Freezing and melting of a sessile water droplet on a horizontal cold plate