Abstract
In this paper, it is reported that the histidine-silane derivative Boc-His(Boc)-CONH-(CH 2) 3Si(OEt) 3 can be polymerized via the sol-gel method or can be grafted on a silica surface. The obtained organosilicas bear histidine molecules covalently bonded on the inorganic matrix. Their Cu(II) complexes have been evaluated as oxidation catalysts for the conversion of 3,5-di- tert-butylcatechol (DTBC) to 3,5-di- tert-butylquinone (DTBQ) in the presence of dioxygen.
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