Deep-level transient spectroscopy characterization of electrical traps in p-type multicrystalline silicon with gettering and hydrogenation process

Abstract

In p-type multicrystalline silicon solar cells, defects in silicon bulk are well known to act as carrier recombination centers and considerably affect the conversion efficiency of cells. In this study, effective minority carrier lifetime (τeff) mapping and deep-level transient spectroscopy (DLTS) data were utilized to evaluate gettering efficiency and hydrogenation passivation in bulk defects. Microwave photoconductivity decay method was used to illustrate the effect of phosphorus gettering behavior and hydrogenation process on the bulk carrier lifetime of multicrystalline silicon. Results showed that τeff drastically improved after gettering and further increased after hydrogenation. DLTS results further revealed six traps corresponding to interstitial iron (Fei), Fe–O complex, FeB complex, vanadium, Fei complex and divacancy oxygen. The main trap in a nongettered sample was related to Fei, with two deep levels at about EV + 0.373 and EV + 0.470 eV. However, the Fei complex was the main trap in the gettered sample, with two deep traps at about EV+0.390 and EV+0.442 eV. Finally, we concluded that Fei defect and FeB complex can be significantly removed by phosphorus diffusion gettering. Moreover, divacancy-oxygen complexes, vanadium and Fe–O defects were effectively passivated by hydrogenation process. Fei complex, however, was hardly removed by these two process.