Deep desulfurization of diesel oil oxidized by Fe (VI) systems

Abstract

Fe (VI) compound, such as K 2FeO 4, is a powerful oxidizing agent. Its oxidative potential is higher than KMnO 4, O 3 and Cl 2. Oxidation activity of Fe (VI) compounds can be adjusted by modifying their structure and pH value of media. The reduction of Fe (VI), differing from Cr and Mn, results in a relatively non-toxic by-product Fe (III) compounds, which suggests that Fe (VI) compound is an environmentally friendly oxidant. Oxidation of model sulfur compound and diesel oil by K 2FeO 4 in water-phase, in organic acid and in the presence of phase-transfer catalysts is investigated, respectively. The results show that the activity of oxidation of benzothiophene (BT) and dibenzothiophene (DBT) is low in water-phase, even adding phase-transfer catalyst to the system, because K 2FeO 4 reacts rapidly with water to form brown Fe(OH) 3 to lose ability of oxidation of organic sulfur compounds. The activity of oxidation of the BT and DBT increases markedly in acetic acid. Moreover, the addition of the solid catalyst to the acetic acid medium promotes very remarkably oxidation of organic sulfur compounds. Conversions of the DBT and BT are 98.4% and 70.1%, respectively, under the condition of room temperature, atmospheric pressure, acetic acid/oil ( v/ v) = 1.0, K 2FeO 4/S (mol/mol) = 1.0 and catalyst/K 2FeO 4 (mol/mol) = 1.0. Under the same condition, diesel oil is oxidized, followed by furfural extraction, the results display sulfur removal rate is 96.7% and sulfur content in diesel oil reduces from 457 ppm to 15.1 ppm.