Abstract

The optical absorption spectra of short-lived species generated in aerated aqueous solutions of 3,5-dihydroxytoluene, a representative of alkylhydroxybenzenes, by the action of single electron beam pulses were recorded. The decay curves recorded at different wavelengths differ from each other, thus suggesting that the transient species react with one another and with water via a complex mechanism and making it possible to discriminate between individual bands characterizing each particular species in the overall spectrum. Two procedures for analyzing complex absorption spectra were employed: (i) with the use of spectra observed at different time delays after the electron pulse and (ii) with deconvolution into a sum of Gaussians.

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