Abstract
The title compound, [C8H18N]+·[B5O6(OH)4]−, has been synthesized under mild solvothermal conditions in the presence of N,N-dimethylcyclohexylamine acting as a template. The structure consists of pentaborate [B5O6(OH)4]− anions connected through O—H⋯O hydrogen bonds into a three-dimensional framework, with large channels along [100], [010] and [001] directions. The [C8H18N]+ cations reside in the channels, interacting with the framework through N—H⋯O hydrogen bonds.
Highlights
The title compound, [C8H18N]+[B5O6(OH)4], has been synthesized under mild solvothermal conditions in the presence of N,N-dimethylcyclohexylamine acting as a template
The [C8H18N]+ cations reside in the channels, interacting with the framework through N—H O
Symmetry codes: (i) −x+1, −y+2, −z+1; (ii) −x, −y+2, −z+2; (iii) −x+1, −y+2, −z+2; (iv) −x+1, −y+1, −z+2
Summary
R factor = 0.045; wR factor = 0.120; data-to-parameter ratio = 15.2. The title compound, [C8H18N]+[B5O6(OH)4], has been synthesized under mild solvothermal conditions in the presence of N,N-dimethylcyclohexylamine acting as a template. Anions connected through O—H O hydrogen bonds into a three-dimensional framework, with large channels along [100],. The [C8H18N]+ cations reside in the channels, interacting with the framework through N—H O hydrogen bonds
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