Abstract

The endoperoxides 6 and 7 , respectively 9-methoxy- and 1-methoxy-7,8-dioxabicyclo[4.2.2]deca-2,4,7-trienes, and the urazoles 8 and 9 , respectively 9-methoxy- and 2-methoxy-7,8-diazantricyclo[4.2.2]deca-2,4,9-trien- N -methyl-7,8-dicarboximide, were obtained in the cycloaddition of singlet oxygen and 4 -methyl-1,2,4-triazoline-3,5-dione (MTAD) to methoxycyclooctatetraene (MCOT).

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