Abstract
Temperature and time dependence of the phase formation in the (Cu0.5,Tl0.5)-1234 composition have been studied. The liquid–vapour deposition mechanism for the formation of 12(n − 1)n superconducting phases is presented. XRD, SEM, EDS and weight loss data are discussed. Samples were superconducting with maximum Tc and Jc (at 60 K and 0.5 T), determined from M(H) loops of 118 K and 4 × 105 A cm−2, respectively.
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