Abstract
The 35Cl nuclear magnetic resonance (NMR) spectroscopy was first used to study the crystallization of erbium-doped fluorochlorozirconate glass in the ZrF4–BaF2–BaCl2–LaF3–AlF3–NaF system. It has been shown that crystallization results in the increasing homogeneity of electronic structure on chlorine atoms and a narrowing of the NMR line. The glass being crystallized, erbium cations are displaced into the fluoride phase.
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