Abstract
Crystal structures of the alkaloids vasicinone and peganidine hydrochloride were studied by x-ray structure analysis. The configurations of asymmetric centers C4 and C9 in peganidine were determined. The hydroxyl and acetonyl groups were mutually syn-positioned relative to the tricyclic plane. H-bonds involving the Cl ion, which connected molecular cations transformed by 21 screw axes, were formed in the peganidine hydrochloride crystal. H-bonds between the C4 carbonyl and the C9 hydroxyl transformed by a glide plane were formed in the vasicinone crystal. The N1 atom was not involved in forming intermolecular H-bonds.
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