Abstract
Abstract We have determined the crystal and molecular structure of trans-bis(acetonitrile)dichloroplatinum(II). Crystallographic data for trans-Pt(CH3CN)2Cl2: monoclinic, space group P21/c, a = 5.0453(9), b = 6.9896(5), c = 11.962(1) Å , β = 101.40(1)°, V = 413.5 Å3, Z = 2 ,Dx = 2.796 g cm-3,μ(CuKα) = 377.5 cm-1, R = 0.0502, wR = 0.0529 for 43 variables and 807 reflections with F > 3σ(F). The Pt atom is in a planar configuration with N and Cl atoms in trans positions. The shortest distance between two Pt atoms corresponds to the length of the crystallographic a-axis (5.045 Å). Additionally, we present optical absorption data of the cis-and trans-isomer.
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