Abstract
In the crystal structure of the title molecular salt, C6H9N2O2S+·H2PO4 −, the sulfomylalinium cations and the dihydrogen phosphate anions form independent [100] chains through Ns—H⋯O (s = sulfamoyl) and O—H⋯O hydrogen bonds, respectively. The chains are cross-linked by Na—H⋯O (a = amine) hydrogen bonds, generating (010) sheets. Two C—H⋯O hydrogen bonds involving diametrically opposite C atoms in the benzene ring of the cation as donors form chains parallel to [202] in which P=O and P—OH groups are acceptors. Together, these interactions lead to a three-dimensional network.
Highlights
In the crystal structure of the title molecular salt, C6H9N2O2S+H2PO4, the sulfomylalinium cations and the dihydrogen phosphate anions form independent [100] chains through Ns—H O (s = sulfamoyl) and O—H O hydrogen bonds, respectively
The chains are cross-linked by Na—H O
Atoms in the benzene ring of the cation as donors form chains parallel to [202] in which P O and P—OH groups are acceptors. These interactions lead to a threedimensional network
Summary
In the crystal structure of the title molecular salt, C6H9N2O2S+H2PO4, the sulfomylalinium cations and the dihydrogen phosphate anions form independent [100] chains through Ns—H O (s = sulfamoyl) and O—H O hydrogen bonds, respectively. The chains are cross-linked by Na—H O (a = amine) hydrogen bonds, generating (010) sheets. H O hydrogen bonds involving diametrically opposite C atoms in the benzene ring of the cation as donors form chains parallel to [202] in which P O and P—OH groups are acceptors. Together, these interactions lead to a threedimensional network
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More From: Acta crystallographica. Section E, Structure reports online
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