Abstract
A new (0D) hybrid (n-C8H17NH3)2CoCl4 has been synthesized and characterized electrically and thermally. Moreover, single crystal X-ray diffraction evidenced that the hybrid belongs to a monoclinic system with a space group P21/n. The mean molar magnetic susceptibility (χ¯M)was measured as a function of temperature (80 K < T < 373 K). The results indicate that the hybrid behaves as paramagnetic material with a sign of antiferromagnetic interaction at very low temperatures.The structural origin of the anomaly that observed at 340 K from electrical measurements, has been confirmed by DSC thermogram. Based on the hydrogen bonding systems, one can suggest the strategy of the structural phase transition.
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