Abstract
The room temperature crystal structure of BaZnFe 6O 11 Y-type ferrite is refined from X-ray single crystal data. This compound is trigonal (space group R 3 m); expressed in the hexagonal axes, the cell parameters are: a = 5.875(1) Å and c = 43.571(6) Å and there are 6 formula units in this nonprimitive cell. The location of the Zn 2+ cation among the six sublattices of the structure is given: this cation lies in the only tetrahedral sites with a marked preference for the S-block ones (71%). A complete description of the structure is done and the superexchange interactions paths are given.
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