Abstract
AbstractNa5[FeO3][OH] has been obtained from a redox reaction between iron metal and CdO in the presence of Na2O and NaOH at 450 °C (5 d) as red crystals. The structure has been determined from single crystal data (Pnma, Z = 8, a = 990.94(7) pm, b = 1016.41(7) pm, c = 1185.35(8) pm, wR2 = 0.050) and evaluated by MAPLE calculations. In addition, we present experimental single‐crystal IR and Raman spectroscopic data to discuss aspects of the isolated [FeO3]4– complexes and non‐coordinating hydroxide in comparison with the respective cobalt compounds. Additional ab‐initio lattice dynamic calculations are included for comparison.
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