Abstract
The reaction of (1,4,7-triazaheptane)Cu(NO 3) 2 with 2-amino-5-methyl-1,3-thiazole (amtz) yields the compound [(amtz)(dien)Cu](NO 3) 2 (dien=1,4,7-triazaheptane). The compound has been characterised by elemental analyses, molar conductance and magnetic measurements, as well as by its electronic and IR spectra and X-ray diffraction. There are two crystallographically discernible cations [(amtz)(dien)Cu] 2+ and four NO 3 − in the asymmetric unit of the structure. Dien is tridentate with mean Cu–N=1.997(5) and 2.021(5) Å in the two Cu-ions, respectively. Amtz is coordinated through its endocyclic N with Cu–N=2.063(7) and 1.945(6) Å in the two ions, respectively. The CuN 4 unit is approximately square planar and almost perpendicular to the tz plane. Both the cations make two long (trans-Cu…O=2.6–2.7 Å) contacts. Ab initio calculations on the constituent fragments [(dien)Cu] 2+, [(amtz)Cu] 2+ and [(dien)(amtz)Cu] 2+ reproduced the average molecular structure parameters of the two Cu-ions in the unit cell and also helped interpret the details of the molecular structure as well as the assignment of the vibrational and electronic spectra.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.