Abstract
The dynamics of the Cl+SiH4 reaction has been studied using the universal crossed molecular beam method. Angular resolved time-of-flight spectra have been measured for the channel SiH3Cl+H. Product angular distributions as well as energy distributions in the center-of-mass frame were determined for the channel. Experimental results show that the SiH3Cl product is mainly backward scattered relative to the Cl atom beam direction, suggesting that the channel takes place via a typical SN2 type reaction mechanism.
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