Abstract
Proton transfer is the most probable type of reaction observed in a number of ion—molecule interactions involving permanent dipoles. Integrated cross sections, which are unusually large, are described in terms of an ion—dipole pair oriented near the position of minimum energy at low relative velocity. As the relative velocity is increased, this alignment becomes less likely. The energy-dependent cross section is eclipsed at high relative velocity by the ``hard'' cross section which does not vary with energy. Proton affinities are estimated for several alkyl cyanides. Some of the reported reactions appear to involve excited states of the primary ions.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.