Craze intersections in biaxially-stressed polystyrene

Abstract

Crazes are produced on two orthogonal planes in both thin film and macroscopic samples of polystyrene by sequentially applying two orthogonal tensile strains e1 and e2. Although many crazes produced by the second strain e2 (secondary crazes) are stopped when they meet a primary craze, some intersections occur. The fraction of craze meetings resulting in intersection increases from 20% at e1=e2=3% to 55% at e1=e2=5%; intersections also occur preferentially in thin regions of primary crazes. The craze fibril structure in the intersection has a much lower fibril volume fraction, vf, than either of the two crazes from which it formed. The fibril volume fraction in the intersection is approximately given by the product of the fibril volume fractions of the two crazes, in agreement with a prediction based on the surface drawing mechanism of craze thickening. At higher strain levels the vfs of the intersections are lower, leading to higher fibril stresses and enhanced fibril fracture; an increasing fraction of intersections breaks down to form large voids at these higher strain levels. Fractography of macroscopic samples containing intersecting crazes demonstrates that voids formed at the intersections can act as nuclei for cracks causing premature fracture of the material.