Abstract

An electrochromic system offering ease of color tunability was constructed using a triple-decker PtII complex. The divalent complex shows electrochemically quasi-reversible two-electron transfer coupled with the coordination/dissociation of axial ligands forming higher valent Pt(+2.67) species. This complex exhibits characteristic colors from red to purple, blue, and cyan depending on coexisting halide ions. The triple-decker structure provides a novel multicolor electrochromic system with favorable stability and reversibility. More information can be found in the Full Paper by M. Yoshida, M. Kato et al. on page 7669.

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