Abstract
An attempt has first been made to correlate the cationic charge of transport ( α 1 ∗ ) with the nonstoichiometry (δ) as well as with the reciprocal oxygen exponents of the conductivity and the nonstoichiometry for the system C 1− δ O . The cationic charge of transport tends to increase monotonically, but at a lesser and lesser rate, with δ at a given temperature and appears to be linearly correlated with reciprocal oxygen exponents. These correlations suggest that the charge of transport may be viewed as a measure of the relaxation effect between the surrounding electronic charge cloud and the central cation vacancy (V Co ″ )or as the number of holes associated with the vacancy in an average sense which reduces the effective charge of the vacancy.
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