Abstract
Solubility data of CO 2 in aqueous N-methyldiethanolamine (MDEA) solutions of concentration (2.52, 3.36, and 4.28) kmol/m 3 were obtained at temperatures (313, 323, and 343) K and partial pressures ranging from about (30 to 5000) kPa. A thermodynamic model based on extended Debye–Hückel theory was applied to predict and correlate of CO 2 solubility in various aqueous amine solutions. The effect of piperazine (PZ) concentration on CO 2 loading in MDEA solutions was determined at PZ concentration (0.36, 0.86, and 1.36) kmol/m 3. Using experimental data in various temperatures the interaction parameters of activity coefficient model for these systems were determined. The results show the model consistency with experimental and literature data and PZ is beneficial to the CO 2 loading. The comparison of results of this study with previous data work shows the wide range of CO 2 loading considered in this work and the better agreement of model with experimental data. The average absolute relative deviation percent ( δ AAD) for all data points were 8.11%.
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