Abstract
AbstractThe first stereoselective synthesis of (Z)‐β‐(tosyloxy)alkenyl iodide has been developed from (aryl)[(E)‐β‐(tosyloxy)alkenyl]iodonium tosylates by using a CuI catalyst. The products of this reaction have been utilized for the diversity‐oriented synthesis of trisubstituted alkenes, and a formal synthesis of the anticancer compound (Z)‐tamoxifen is described.
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