Abstract
L'alkylation de l'acetate de cuivre II avec des reactifs de dialkylmagnesium (MgMe 2 , Mg(CH 2 SiMe 3 ) 2 ) fournit des complexes du cuivre du type paire ions ou neutres: [Cu(PMe 3 ) 4 ][CuMe 2 ], CuMe(PMePh 2 ) 3 , Cu(CH 2 SiMe 3 )(PMePh 2 ) 3 , [Cu(PMe 2 Ph) 4 ][Cu(CH 2 SiMe 3 ) 2 ]. La structure cristalline de Cu(PMe 3 ) 4 [CuMe 2 ] est effectuee
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