Abstract
In the reaction of FeIII(por) species with [LCuI(KMeCN)]+ and O2 to give µ-oxo [(por)FeIII–O–CuIIL]+3(por = porphyrinate, L = tetradentate ligand), copper–dioxygen adducts or their decomposition products must be present, otherwise [(por)FeIII–OH] or [(por)FeIII–O–FeIII(por)] products appear; a novel synthesis ot square-planar FeII(por) is also described.
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