Abstract
Broad tolerance: A step further in the enantioselective Cu-catalyzed conjugate addition of R2Zn reagents to enoyl systems is taken by using sterically encumbered α′-oxy enone templates (see scheme). The method constitutes an advanced entry to enantioenriched β-branched carboxylic acids and aldehydes with a broad R2Zn and functional group tolerance.
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