Abstract

Tb3+, Er3+co-doped K2GdZr (PO4)3samples were prepared by solid-state reaction method and their photoluminescence (PL) properties were investigated in ultra-violet (UV) and vacuum ultra-violet (VUV) region. The results indicate that the energy transfers from Er3+to Gd3+and from Gd3+to Tb3+required for occurring of visible quantum cutting through down-conversion are efficient. In this cooperative energy transfer process, Gd3+is used as an intermediate of energy transfer between Er3+and Tb3+. The optimal quantum efficiency (QE) of this co-doped system K2GdZr (PO4)3: Er3+, Tb3+phosphor reached to 110%, suggesting a potential visible quantum cutting phosphor in practical application.

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