Conversion of molybdenite by a mineral phase reconstruction method and leaching kinetics of its product

Abstract

Determined by the unique S-Mo-S sandwich layer structure, molybdenite is so chemical inert and hydrophobic that it is quite refractory in hydrometallurgical route. To improve Mo leaching by changing mineral structure of molybdenite prior to leaching might be a potential alternative. In this work, a mineral phase reconstruction (MPR) method is presented to treat molybdenite. The transformation of molybdenum-bearing sulfides by this method and leaching performance of MPR product were investigated. Results show that molybdenite can be reconstructed to a ternary sulfide FexMo6S8 by smelting with iron. The ternary sulfide can be leached much faster and more complete than molybdenite under the same conditions. Moreover, laboratory research and commercial practice show that sulfur of molybdenite being totally oxidized to sulfate. But as for the ternary sulfide, sulfur was converted into elemental state. An autocatalytic reaction kinetic equation was applied to fit the experimental data of MPR products leaching with HNO3-H2SO4 mixed solution. The apparent activation energy was calculated to be 76kJ·mol−1 indicating the process being chemical reaction controlled. The reaction is of the 1.5 and 0.6 order related to HNO3 and H2SO4 concentration respectively. Finally, a kinetic equation is established for the leaching reaction.