Controlling the Surface Morphology of ZnO Nano-Thin Film Using the Spin Coating Technique.

Abstract

Zinc oxide (ZnO) thin films are significant in various electronic applications. This study introduced an efficient, simple, low cost and timesaving method to obtain an extended and uniform ZnO thin film with tunable surface morphology over the substrate using the spin coating technique. Different concentrations of zinc acetate dehydrate were used as precursor solutions mixed with polyvinyl alcohol as a binding polymer to obtain the film’s uniformity and to relieve thermal expansion that may cause a wrinkled surface. Synthesized films were characterized using X-ray diffraction (XRD), X-ray spectroscopy (XPS), scanning electron microscopy (SEM), atomic force microscopy (AFM) and ellipsometry. Findings show that the average size of ZnO particles was less than 50 nm in a uniform film over the whole substrate area regardless of the presence or absence of wrinkles. Additionally, this method was quite fast, attaining the desired viscosity in less than one hour in comparison with the time-consuming aging method, which requires approximately 24 h to achieve the required viscosity.