Controlled synthesis from alginate gels of cobalt–manganese mixed oxide nanocrystals with peculiar magnetic properties

Abstract

Tailored cobalt–manganese mixed oxide nanoparticles are obtained from ionotropic gels of alginate, a seaweed-derived carboxylic-functionalized polymer. (Co,Mn)3O4 phases are formed by low-temperature calcination of the alginate aerogels. Cubic spinel or tetragonal hausmannite structures are formed if, respectively, cobalt or manganese is the main cation. Stable nano-sized mixed oxides are formed in the whole range of composition of the solid solution by calcination of the aerogel precursors at 450°C. The manganese-rich oxides are more dispersed than the cobalt-rich oxides, with surface areas higher than 80m2g−1. The organization of the oxide nanocrystals in arrays reminiscent of the fibrillar structure of the parent gel prevents them from packing and confers them peculiar magnetic properties in terms of coercivity and magnetoresistance.