Constructing extrinsic oxygen vacancy on the surface of photocatalyst as CO2 and electrons reservoirs to improve photocatalytic CO2 reduction activity

Abstract

Constructing own oxygen vacancies in the photocatalysts is a very promising method to improve their photocatalytic CO2 reduction activity. However, some catalysts have excellent stabilities, making it difficult for them to construct their own oxygen vacancies. To simplify the above difficulty of stable photocatalysts, constructing extrinsic oxygen vacancies on their surface as a novel idea is proposed. Here, a stable TiO2 nanosheet is chosen as a research object, we uniformly deposited BiOCl quantum dots on their surface via a simple adsorption-deposition method. It is found that BiOCl quantum dots are able to simultaneously self-transform into defective BiOCl with many oxygen vacancies when the photocatalyst is performed photocatalytic CO2 reduction. These extrinsic oxygen vacancies can act as “CO2 and photo-generated electrons reservoirs” to improve CO2 capture and accelerate the separation of photogenerated electrons and holes. For the above reasons, the modified TiO2 showed obvious enhancement of photocatalytic CO2 reduction compared to pristine TiO2 and BiOCl. This work may open a new avenue to broaden the use of oxygen vacancies in the process of photocatalytic CO2 reduction.