Constructing an ultrastable imidazole covalent organic framework for concurrent uranium detection and recovery

Abstract

Uranium is one of the most important strategic resources for the development of the nuclear industry, but its unintended release has created potential environmental and health risks. It is highly desired to explore new methods that enable concurrent uranium monitoring and recovery for environmental protection and sustainable development of the nuclear industry. Here, for the first time, an imidazole fluorescent covalent organic framework (named PyTT-Tp) with ultrastable skeleton and open nanopore channel is synthesized by condensing ammonium acetate, 1,3,5-triformylphloroglucinol and pyrene-4,5,9,10-tetrone. By precisely tailoring complexing ligands, PyTT-Tp shows an excellent uranium recovery capacity of 941.27 mg g−1 and reached equilibrium within 60 min, which can be attributed to dense selective uranium binding sites on the highly accessible open skeleton. In addition, due to the signal amplification of the pyrene-imidazole skeleton, it has an ultra-low detection limit of 4.92 nM UO22+ and an ultra-fast response time (2 s) suitable for on-site monitoring the uranium content of the extracted water. By modulating target complexing ligands, this approach can be extended to the monitoring and recovery of other strategic nuclides.