Abstract
The reaction of [Ph6P3N4H2]+Cl– with sulphur dichloride affords the eight-membered 1,3,5,7,2,4,6,8-thiatriphosphatetrazocine Ph6P3N4SCl, which can be reduced by triphenylantimony to the corresponding thiatriphosphatetrazocinyl radical [Ph6P3N4S]˙; the temperature dependence of the e.s.r. spectrum of this radical provides a unique demonstration of the effects of conformational rigidity in an oligophosphazene skeleton.
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