Abstract
The 2,3,4-tri- O-acetyl-α- and -β- d-arabinopyranosyl azide anomers were studied by the semiempirical quantum-chemical PCILO method. Rotational energy maps for the azide group and the three acetyl groups established the lowest energy minima for the two anomers. Two minima each were found for the azide group setting. The geometry around the anomeric carbon atom was optimized for each conformer. It was observed that the lowest minima found were in the range showing the exo-anomeric effect.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
