Abstract
Conductances of silver acetate in 0–50% (w/w) methanol-water mixtures at 25°C have been measured. The association constants were evaluated using the Shedlovsky extrapolation technique and Fuoss-Hsia equation with Fernandez-Prini coefficients and the results obtained by these two methods were compared. The log K A vs 1 D plot was a straight line passing through the origin in accordance with the Denison-Ramsey theory of ion-pair formation. The results are interpreted in terms of the equilibrium between “Solvent separated ion-pairs” (SSIP) and “Contact ion-pairs” (CIP).
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