COMPRESSIVE MODULUS OF FERRITE CONTAINING POLYMER GELS

Abstract

The mechanical properties of magnetic gel have been investigated. Magnetic gels, which consist of finely dispersed powder of barium ferrite ( BaFe 12 O 19) and poly vinyl alcohol (PVA), have been synthesized. The diameter of barium ferrite is less than 45 μm. The magnetic gels varying with ferrite concentration, crosslinking densities were prepared by mixing 10 wt.% PVA aqueous solution and barium ferrite using glutaraldehyde as a crosslinking agent in the presence of HCl. The diameter of barium ferrite is large enough to have a permanent magnetic moment. We applied a 10 kOe magnetic field in order to saturate the magnetic moment of barium ferrite. After magnetization, the compressive modulus was estimated with an ultrasonic method in order to find the influence of magnetization. Ultrasonic measurements were carried out using burst waves at 10 MHz and 295.5 K. The modulus of magnetized gel was found to depend on the concentration of magnetic substance, the crosslinking density, and the degree of swelling. It was clear that the modulus of magnetized gel was higher than the gel without magnetization for all samples. The change in modulus to the initial modulus ΔM′/M′o for 10 wt.% and 15 wt.% of ferrite concentration was about 0.28% and 0.4% in a lower density region, respectively. Moreover, the change in modulus ΔM′/M′o was constant in a lower density region however it strongly depends on the density in a higher density region. When the stress direction is perpendicular to the magnetization, the change in modulus increased. On the contrary, the change in modulus decreased when the stress direction is parallel to the magnetization. As increasing the density, the distance between magnetic substances become short and therefore the magnetic interaction is more significant in a higher density region.