Abstract
The dissolution of DyI2 in diamine Me2N(CH2)3NH2 (DMDA) is accompanied by the disproportionation of the salt, hydrogen evolution, and oxidation of DyII to DyIII. The [Dy(DMDA)8]I3 complex (1) was isolated from the solution. The neodymium amide amine complex (PriNH)NdI2(IPA)4 was produced by the reaction of NdI2 with isopropylamine (IPA). The recrystallization of this complex from IPA afforded the NdI3(IPA)4 complex (2). The recrystallization of (PriNH)NdI2(IPA)4 from a toluene-IPA mixture gave the complex with five amine ligands, NdI3(IPA)5 (3). The structures of compounds 1, 2, and 3 were established by X-ray diffraction.
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