Abstract
Reaction of K[(OPPh 2) 2N] with UO 2(NO 2) 2 · 6H 2O resulted in the formation of compound [UO 2[(OPPh 2) 2N] 2] 3 ( 1). Single-crystal diffraction analysis of 1 reveals an elaborated and unique trinuclear uranyl compound, where the central UO 2 moiety exhibits Lewis basic properties through an equatorial U⋯O U O⋯U bridging towards two outer uranyl units comprised in a six-membered ring array. The central and outer UO 2 groups are also bridged by means of four eight-membered rings containing the ancillary ligand. The overall morphology of this compound may be regarded as a linear U 3O 2 core engaging two different types of environments for the uranium atoms.
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