Abstract

Compatibility of structural materials (ferritic steel, vanadium-based alloy and molybdenum) with molten LiF–BeF 2 mixture under the atmosphere containing O 2, H 2O and HF was studied using thermodynamical calculation of chemical equilibria at 823 K. It was clarified that the oxidation of structural materials would have precedence over fluorination with coexistence of oxidizing species though fluorination was found under the atmosphere containing HF. Then, these materials would have satisfactory corrosion resistance if generated oxides function as protective scales.

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