Comparison of thermal conductivity data for partially stabilized zirconia with values derived from thermal diffusivity results

Abstract

The thermal conductivity of partially stabilized zirconia was measured over the temperature range 320–1273 K using the radial heat flow method. The data have an absolute uncertainty of about ±2% and repeat measurements showed no evidence of changes in the thermal conductivity at high temperatures. This also was true for the thermal diffusivity data, which were obtained in vacuum over the temperature range 300–1473 K. Both sets of thermal conductivity data pass through minima at high temperatures. Quantitative differences were observed in the temperatures and thermal conductivities of the two minima. The results were analyzed by assuming parallel conduction by phonons and photons, and the phonon component was identified by fitting lower-temperature data. Extrapolating this curve allowed identification of the photon contribution to the thermal conductivity at high temperatures. The photon contribution approached a T3 function and was larger in the thermal conductivity specimens. The difference in the photon contributions correlates with changes in the optical properties of the samples produced during the high temperature measurments.