Abstract

Potato leaf, stem and tuber samples have been analysed for nitrogen concentration [N], by three methods; Kjeldahl digestion, Dumas combustion, and near infra-red reflectance (NIR) spectroscopy. Models to estimate [N] from NIR have been developed using either Kjeldahl or Dumas for calibration. Estimates of [N] from all three methods, are highly correlated. However, [N] measurements by Kjeldahl and Dumas are not in agreement. Kjeldahl has a recovery rate of ca. 98% organic-N and variable recovery of inorganic-N. Dumas measures both organic- and inorganic-N with a recovery rate of 100%. The suitability of Kjeldahl as an analytical technique must be questioned when NIR methods are available which will give accurate [N] values quickly, safely and cheaply.

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