Abstract
ABSTRACTIn order to compare the separation of Ir(IV) and Rh(III) between SnCl2 and ascorbic acid as a reducing agent, solvent extraction with Cyanex 921 and Cyanex 301 was investigated in the HCl concentration range from 1 M to 9 M. Addition of both SnCl2 and ascorbic acid led to the selective extraction of rhodium by the two extractants, leaving Ir(III) in the raffinate. Since tin was selectively extracted over Rh(I) in the presence of SnCl2, it is necessary to separate Rh(I) and tin by selective stripping from the organic phase. In the presence of ascorbic acid, the extraction percentage of rhodium by Cyanex 921 was much smaller than that in the presence of SnCl2. UV spectra was analyzed to verify the reduction reaction of both metal ions. FT-IR was analyzed between fresh and loaded organic solution. The reduction of Ir(IV) and Rh(III) in the presence of ascorbic acid was explained. Selective stripping of Rh(I) over tin from the loaded Cyanex 921 was obtained by the mixture of HCl and (NH2)2CS.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
