Comparison of oxy-fuel preheated combustion characteristics of high- and low- volatility carbon-based fuels

Abstract

A comparative evaluation and analysis study of combustion characteristics, main pollutant emission behaviors, and fuel-N conversion paths of high- and low- volatility carbon-based fuels are conducted under O2/CO2 atmospheres in a preheating combustion reactor, i.e., CFB. Compared with conventional air combustion, the oxy combustion with high oxygen concentrations from 21% to 27.3% is studied. The studies show that the net calorific value of the preheated coal gas of semi-coke in O2/CO2 is up to 2 times that in air, and the net calorific value of the preheated coal gas of bituminous coal in O2/CO2 is up to 1.3 times that in air. During the preheating process of semi-coke, CH4 and HCN occupy a discreet proportions of preheating coal gas. Fuel characteristics and preheating atmosphere have no effect on the particle size of preheated coal char. Under an O2/CO2 atmosphere, the highest BET surface area of preheated coal char of bituminous coal is up to 30 times that of raw coal and that of semi-coke is up to 40 times that of raw coal. The carbon structure modification ratio of preheated coal char during the preheating process of bituminous coal is larger than that during the preheating process of semi-coke. With the increase in the concentration of oxygen in the primary stream, the NO emission decreased during the bituminous coal combustion process but increased during the semi-coke combustion process. In addition, the main generation path of NO in the reduction zone in O2/CO2 is NH3-NH2-NH-HNO-NO. In O2/CO2, the total promotion effect of reactions on NO formation in the combustion process of semi-coke preheated fuel is larger than that of bituminous coal.