Comparison of leachable trace element levels in coal gasifier ash with levels in power plant ash

Abstract

The levels of 14 trace elements in leachates from three types of ash of a common origin coal were compared. The study was conducted over a one year period at the Kosovo plant in Obilic, Yugoslavia comparing coal gasifier ash with fly ash and bottom ash from a coal-fired power plant using lignite from the Dobro Solo mine. Results obtained indicate that levels of Sb, As, Be, Cr, Cu, Pb, Mo, Ni and Zn in gasifier ash leachate were similar to those in fly ash leachate. Barium levels in gasifier ash leachate averaged 2.7 times that in fly ash and selenium levels averaged 0.33 times. The average ratio for the total set was 0.99. The set average, relative to bottom ash, was 2.1 with the nickel ratio (RNi = 0.31) differing significantly from the average. Metal oxides, CaO, MgO, Na2O, K2O and MgO, in the Kosovo gasifier ash were found at levels similar to those in Kosovo fly ash, and except for K2O, were approximately twice those in bottom ash. Concentration levels of all components showed relatively small variations averaging 50% of their mean annual concentration over the test period.