Comparison of adsorption equilibrium models for the study of CL −, NO 3− and SO 42− removal from aqueous solutions by an anion exchange resin

Abstract

The removal of chloride, nitrate and sulfate ions from aqueous solutions by a macroporous resin is studied through the ion exchange systems OH −/Cl −, OH −/NO 3 −, OH −/SO 4 2−, and HCO 3 −/Cl −, Cl −/NO 3 −, Cl −/SO 4 2−. They are investigated by means of Langmuir, Freundlich, Dubinin-Radushkevitch (D-R) and Dubinin-Astakhov (D-A) single-component adsorption isotherms. The sorption parameters and the fitting of the models are determined by nonlinear regression and discussed. The Langmuir model provides a fair estimation of the sorption capacity whatever the system under study, on the contrary to Freundlich and D-R models. The adsorption energies deduced from Dubinin and Langmuir isotherms are in good agreement, and the surface parameter of the D-A isotherm appears consistent. All models agree on the order of affinity OH − < HCO 3 − < Cl − < NO 3 − < SO 4 2−, and distinguish high energy processes (OH −/Cl −, OH −/NO 3 −, OH −/SO 4 2−, Cl −/SO 4 2−) from lower energy systems (HCO 3 −/Cl −, Cl −/NO 3 −). The D-A and D-R models provide the best fit to the experimental points, indicating that the micropore volume filling theory is the best representation of the ion exchange processes under study among other adsorption isotherms. The nonlinear regression results are also compared with linear regressions. While the parameter values are not affected, the evaluation of the best fitting model is biased by linearization.