Abstract

Hydrotalcite is an anionic clay mineral (layered double hydroxide) whose general formula is [M(II)1−x M(III) x (OH)2] x+X / − ·mH2O. Anionic clays with a hydrotalcite-type are widely used as useful precursors of multicomponent catalysts. Hydrotalcites with Ni/Al molar ratio 2.5 have been synthesised both by the coprecipitation method, starting with nickel and aluminium nitrates and by the sol-gel method, using nickel acetylacetonate and aluminium isopropylate as precursors. The NiO-Al2O3 oxidic forms have been obtained by the thermal treatment of the precursors at 450°C and 900°C, respectively, and were characterised by DTA, XRD, IR spectroscopy and temperature programmed reduction (TPR). TPR clearly demonstrated a higher reducibility of the oxidic forms derived from the sol-gel synthesised precursors.

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