Comparative experimental study on the co-firing characteristics of water electrolysis gas (HHO) and lean coal/lignite with different injection modes in a one-dimensional furnace

Abstract

Zero-carbon fuels (H2/NH3) replacing coal co-firing is a promising way to address carbon emissions. Hydrogen co-firing helps improve combustion stability at low loads and control pollutant emissions. This study used a safer water electrolysis gas (HHO) for the multi-coal co-firing adaptability test. The effects of HHO injection mode and flow rate on combustion intensity, flue gas emissions, and fly ash characteristics were investigated. The results showed that HHO and lean coal/lignite co-firing could significantly increase the combustion temperature. The maximum temperature increases after co-firing were 108 °C and 95 °C. As the HHO increased, the CO2 in lignite co-firing increased, and CO and unburnt carbon decreased, while the opposite results were observed for lean coal (LC). At the 2200L/h HHO co-firing, CO2 decreases by 14.46 % and 27.22 % for LC premixed co-firing (PC) and staged co-firing (SC). Compared to SC, PC is more conducive to promoting the complete combustion of coke. The NOX emissions of HHO/LC co-firing are lower than those of pure coal, reaching the lowest value of ∼ 9 ppm under SC. As the HHO increases, the NOX of Lignite-PC first increases and then slowly decreases, while Lignite-SC has the opposite effect. Although various NOX emission trends are observed under different conditions, the results are dominated by a common mechanism − the competition between NOX reduction caused by HHO gas and the increase in co-firing temperature on NOX generation. The NOX of SC is all lower than that of PC. The SO2 emission from the LC co-firing decreases with the increase of HHO, while the SO2 from lignite increases. The SO2 of LC-SC can be reduced from ∼ 142 ppm to 0 ppm. HHO gas injection inhibits the release and oxidation of sulfur in lean coal. The differences in coal types lead to different changes in SO2 of co-firing. HHO gas reduced the SO3 content of lignite fly ash by 38.01 %. The high-temperature reduction atmosphere promotes the decomposition of sulfates and increases SO2 emissions. HHO co-firing refines the particle size of fly ash. The ultra-fine and micron particle matter (PM) increases, and the content of PM>100μm in Lignite-SC decreased by 10.32 %.