Abstract

ABSTRACT Magnesium (Mg) dust and magnesium–aluminum (Mg–Al) alloy dust are commonly produced and form a dust cloud in industrial manufacturing processes, which considerably increases explosion risk. This study examined three metal dusts: Mg, 48 mass% Mg–Al alloy, and 91 mass% Mg–Al alloy. A 20-L spherical explosion device was used to investigate the effect of different Mg concentrations. The results revealed that for all the samples, the explosion pressure (P ex) first increased and then decreased for a dust cloud concentration of 100–1000 g/m3. With the increase of dust particle size, the P ex of samples decreased. With the increase of ignition delay time, the P ex of samples first increased and then decreased, reaching the peak at 60 ms. Under identical conditions, when Mg concentration increased, the alloys became less stable. Thermogravimetry-differential scanning calorimetry findings revealed that the oxidation process of samples could be divided into three stages. The initial oxidation temperature of the alloys was lower than that of the pure Mg; however, in its primary oxidation stage, the mass gain rate of the Mg dust was more rapid than that of the Mg–Al alloys. In the oxidation of the alloys, elemental Mg reacted with oxygen first.

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