Abstract
For original paper see J.A.D. Matthew et.al., ibid., vol.13, p.581 (1983). Matthew et. al. derived an expression for the entropy change due to disordering of an ordered one-dimensional equiatomic binary alloy at high temperatures, using the harmonic approximation and assuming a fixed-end boundary. As a first step towards the calculation of entropy changes due to disordering of ordered two- and three- dimensional binary alloys (Bakker 1982, Waegemaekers and Bakker 1983) the present author had already studied the linear chain and was able to derive in a very simple and straightforward way the exact expression for the entropy change of a binary linear chain which changes its state I of order to a state II of order.
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